y yf
01  Direct electron transfer from magnesium to oxygen

Atoms react in order to obtain as many electrons as the noble gas atoms placed next to them in the periodic table of elements:
Photo 3: Magnesium atoms have 2 electrons more than atoms of the noble gas neon. Oxygen atoms have 2 electrons less than neon atoms.
Metal atoms are electron donor, non metals like oxygen are electron acceptor.
The sketch  (Schuphan Knappe, Chemie Buch Verlag Diesterweg 1988, S. 21) illustrates what happens with the smallest particles of Mg and O during the combustion of magnesium (Photo 2).
By not using more than 1 cm of magnesium ribbon and working in a tray with some water in its combustion of magnesium (photo 1) is suitable for student experiments. By this experiment students learn how to find the hottest area of the micro spirit burner.

Material
Tray, goggles, micro spirit burner, stopper of an infusion bottle (stand), scissors, tweezers, sandpaper, periodic table pyramid, water, methylated spirit magnesium ribbon (10 x 4 mm).

Experiment
1. The teacher distributes sandpapered pieces of magnesium ribbon (1 cm).
2. The micro burner is fixed inside the stopper and placed in the middle of the tray.
3. The bottom of the tray is covered with water, the burner is
lit .
4. Hold the magnesium at one edge, light it at the tip of the flame.
5. Extinguish the burner when the reaction has started.
6. Fold and glue a periodic table pyramid.
Observations
Magnesium (Mg) is burning with a bright flame leaving a white brittle substance (Photo 1).
Explanation
Magnesium and oxygen react in an exothermic reaction leaving magnesium oxide (MgO).
Photo 3: Magnesium atoms (12Mg) have 2 electrons more than atoms of the noble gas neon (10Ne), oxygen atoms (8O)  have 2 electrons less than atoms of the noble gas neon (10Ne).
An electron transfer between Mg and O atoms takes place:
Mg donates two electrons, O accepts these 2 electrons, both are transformed into ions with a double charge  Mg  ---> Mg2+  +  2e-                 O    + 2e- ---> O2-
These ions resemble the noble gas neon (10Ne) in their electron number but not in reactivity.

Mg ions and O ions attract each other forming a lattice:                                                                              Mg2+  +   O2-  ---release of heat and light---> MgO(s)


back....... go on...............first published: 25.10.2001................................................last modification: 13.06.2008