You have made Galvanic cells
by combining half cells made of injection bottles:
* A voltage and a current
were observed between Al and Fe
* A
LED gave light when it was connected to Pb and PbO2.
There are not only direct
redox reactions between alcohol and a mixture of dichromate
and sulfuric acid.
1. Photo: Fill the
left half cell with a mixture of methylated spirit and sulfuric acid,
2. the right half cell with
a dichromate solution mixed with sulfuric acid.
3. Connect these two cells
by a wick (for flow of ions) and
the carbon
electrodes with a multimeter by two wires.
Observations:
A voltage of 0.44 Volt and a current of 42.3 µA are measured.
Explanation:
The alcohol molecules around the negative electrode lose
electrons while they are oxidized resulting
in aldehyde.
Dichromate ions around the
positive
electrode take electrons while they are reduced
to Cr3+ ions.
Electrons flow through the
metallic conductors, ions move through the wick.