.
.
.
.
In the experiment for
testing the electric conductivity of sea water chlorine
was formed at a carbon anode.
In the following experiment
you will replace carbon by a piece of cleaned Cola can tin (Fe). Universal
indicator (UI) will be added to the water. A second experiment will be
done without UI..Left: Use the closure of a Cola can (Al) as cathode,
a cleaned piece of its tin (Fe) as anode.(The idea to the following experiments
was published by El-Marsafy: chemarsafE35chemarsafE38)
Observations
Photo
2: Violet colour and gas bubbles at the cathode (Al),
* Anode (Fe): No change
of indicator colour, no gas bubbles, no smell of chlorine.
Observations
Photo
3 and right: During electrolysis without UI and stirring of the liquid
a green solid is formed.
Explanations
Reactions
at the cathode: 2
H2O + 2e- -------red----> 2 OH-(aq)
+ H2 (g)
Reactions at the anode:
Fe (s) -----ox----> Fe2+(aq) + 2e-
Total reaction: 2
H2O + Fe (s) ---redox----> Fe(OH)2(s) + H2
(g)
In
this case the material of the anode was oxidized.